Iron molybdate with an excess of molybdenum oxide (denoted FeMo throughout the paper) is an industrially important catalyst for the selective oxidation of methanol to formaldehyde, which has led to a number of fundamental studies concerning its structure, activity, mechanism, stability and deactivation.1–6 To … See more In order to predict and model the performance of catalysts, their electronic and structural properties need to be studied at an atomic scale as they strongly influence the catalytic … See more The overview of the experimental procedure followed during in situ experiments is given in the ESI,† Fig. S1. The catalyst was first heated to 100 °C in a flow of 10% O2/He. Then the flow was changed to 5% … See more Subsequent heating in an oxidative atmosphere from 200 to 500 °C caused Mo and Fe to reoxidize thereby forming Fe2(MoO4)3. Intermediates phases Fe2O3 and excess MoO3 … See more WebAbstract The electronic state of iron in an iron-molybdenum catalyst in the temperature range of 260-320/sup 0/C for different conditions of treatment of the catalyst and also during the reaction of methanol oxidation was studied. The results obtained were analyzed on the basis of vacancy models.
The Active Molybdenum Oxide Phase in the Methanol Oxidation to …
WebFused-iron catalysts are by far the most studied and widely applied of all the ammonia synthesis catalysts. [2, 31-46]As mentioned in the previous section, fused-iron catalysts … WebApr 7, 2024 · As a result, iron-based catalysts are frequently employed. Iron-based oxides, (oxy)hydroxides, chalcogenides and phosphides, ... (Fig. 1), molybdenum and cobalt form Co 3 Mo phase in this process, indicating that the surface of the catalyst is a complex heterogeneous structure, which is favorable for promoting interfacial charge transfer and ... chinos pia sheffield
Revisiting the Electrochemical Nitrogen Reduction on Molybdenum …
WebJun 17, 2015 · Methanol is oxidised to formaldehyde by the Formox process, in which molybdenum oxides, usually doped with iron, are the catalyst. The active phase of the catalysts and the reasons for the selectivity observed are still unknown. WebAn iron molybdate/molybdenum oxide catalyst (Mo/Fe = 2) was synthesized by a hydrothermal method and the catalyst's performance and compositional changes were followed during selective oxidation of methanol to formaldehyde for up to 600 h. ... From 10 to 600 h on stream leaching of molybdenum from the remaining iron molybdate phase … WebJun 8, 2024 · A series of iron molybdate catalysts were synthesised via a sol gel route using either oxalic acid or malonic acid. Catalysts synthesised using malonic acid were found … chino spectrum towne center chino ca